Most probably you are saving your screenshot in JPEG format (.jpg). JPEG is a "lossy compression" format, designed mainly for real life photos, not for sharp screen capture images. It sacrifices some image quality to better compress graphics files, make them smaller on a disk and load faster over the Internet.
Best, do not use JPEG files at all. Instead, use either BMP format, which does not compress graphics, but preserves 100% quality, or PNG format, which does both good compression, and preserves 100% quality.
If you must use JPEG for some reason, increase the "Image Quality" to 90% or even 95%. The files will be bigger, but will look cleaner. Here is how to set it:
Launch ACA Capture Pro, select menu "Tools->Options", and then click on "Save" tab.